Unison is a file-synchronization tool for OSX, Unix, and Windows. It allows two replicas of a collection of files and directories to be stored on different hosts (or different disks on the same host), modified separately, and then brought up to date by propagating the changes in each replica to the other.
Syncthing replaces proprietary sync and cloud services with something open, trustworthy and decentralized. Your data is your data alone and you deserve to choose where it is stored, if it is shared with some third party and how it's transmitted over the Internet.
git-annex allows managing files with git, without checking the file contents into git. While that may seem paradoxical, it is useful when dealing with files larger than git can currently easily handle, whether due to limitations in memory, time, or disk space.
git-annex is designed for git users who love the command line. For everyone else, the git-annex assistant turns git-annex into an easy to use folder synchroniser.